Go to:
http://www.shopsite.com/help/
and choose your ShopSite product level and ShopSite version from the table to get the help documentation specific to your ShopSite software. Then click on the 'Getting Started with ShopSite' link that will be on the main help page for your version. You will also find the 'Getting Started' section under the Contents tab in the left-hand navigation in the help.
There are also a couple of new video tutorials specific to the ShopSite Setup Wizard and the Order Anywhere feature if you like seeing (and hearing) things better than reading them and are using these features:
http://www.shopsite.com/tutorial/
-Loren